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Issue 71, 2018
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A photocatalytic iminyl radical-mediated C–C bond cleavage/addition/cyclization cascade for the synthesis of 1,2,3,4-tetrahydrophenanthrenes

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Abstract

On the basis of the strategy of iminyl radical-mediated C–C bond cleavage, a visible light photocatalytic radical addition/cyclization cascade is described, providing an efficient and regioselective access to cyanoalkylated 1,2,3,4-tetrahydrophenanthrenes.

Graphical abstract: A photocatalytic iminyl radical-mediated C–C bond cleavage/addition/cyclization cascade for the synthesis of 1,2,3,4-tetrahydrophenanthrenes

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Publication details

The article was received on 28 Jul 2018, accepted on 09 Aug 2018 and first published on 10 Aug 2018


Article type: Communication
DOI: 10.1039/C8CC06145A
Citation: Chem. Commun., 2018,54, 9925-9928
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    A photocatalytic iminyl radical-mediated C–C bond cleavage/addition/cyclization cascade for the synthesis of 1,2,3,4-tetrahydrophenanthrenes

    P. Wang, X. Yu, C. Li, B. He, J. Chen and W. Xiao, Chem. Commun., 2018, 54, 9925
    DOI: 10.1039/C8CC06145A

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