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Issue 58, 2018
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Photoredox-promoted alkyl radical addition/semipinacol rearrangement sequences of alkenylcyclobutanols: rapid access to cyclic ketones

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Abstract

Two photo-catalytic tandem alkyl radical addition/semipinacol rearrangement reactions of cycloalkanol-substituted styrenes with N-acyloxyphthalimides and O-acyl oximes have been documented. These protocols provide efficient access to functionalized cyclic ketones, and feature mild conditions (i.e., visible light irradiation, redox neutral and room temperature), broad substrate scope and excellent functional group tolerance.

Graphical abstract: Photoredox-promoted alkyl radical addition/semipinacol rearrangement sequences of alkenylcyclobutanols: rapid access to cyclic ketones

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Publication details

The article was received on 06 Jun 2018, accepted on 25 Jun 2018 and first published on 26 Jun 2018


Article type: Communication
DOI: 10.1039/C8CC04503H
Citation: Chem. Commun., 2018,54, 8096-8099
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    Photoredox-promoted alkyl radical addition/semipinacol rearrangement sequences of alkenylcyclobutanols: rapid access to cyclic ketones

    S. Yao, K. Zhang, Q. Zhou, Y. Zhao, D. Shi and W. Xiao, Chem. Commun., 2018, 54, 8096
    DOI: 10.1039/C8CC04503H

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