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Issue 55, 2018
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Bis(alkylidynyl)arsines

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Abstract

The synthesis and characterization of the first examples of bimetallic bis(alkylidynyl)arsines, [RAs{C[triple bond, length as m-dash]M(CO)2(Tp*)}2] (M = Mo, R = Ph, Me; M = W, R = Ph, Me, nBu; Tp* = hydrotris(3,5-dimethylpyrazol-1-yl)borate) are described. For the tungsten complexes, these may be prepared by a potentially generalizable route: successive treatment of [W([triple bond, length as m-dash]CBr)(CO)2(Tp*)] with nBuLi, ACl3 (A = P, As) and a nucleophilic source of Rvia the inferred intermediacy of [ClA{C[triple bond, length as m-dash]W(CO)2(Tp*)}2].

Graphical abstract: Bis(alkylidynyl)arsines

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Publication details

The article was received on 25 May 2018, accepted on 06 Jun 2018 and first published on 06 Jun 2018


Article type: Communication
DOI: 10.1039/C8CC04164D
Citation: Chem. Commun., 2018,54, 7649-7652
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    Bis(alkylidynyl)arsines

    B. J. Frogley and A. F. Hill, Chem. Commun., 2018, 54, 7649
    DOI: 10.1039/C8CC04164D

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