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3D Supramolecular self-assembly of [60]fullerene hexaadducts decorated with triarylamine molecules

Abstract

A clickable fullerene hexa-adduct scaffold has been functionalized with twelve triarylamine subunits. The light-triggered self-assembly of this molecular unit leads to honeycomb-like 3D-structures with inner pores of around 10 nm in diameter. The multiple grafting of triarylamine subunits onto a C60 hard-core increases the dimensionality of the self-assembly process by reticulating the 1D nanowires typically obtained from the supramolecular polymerization of triarylamine monomers.

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Publication details

The article was received on 22 May 2018, accepted on 12 Jun 2018 and first published on 13 Jun 2018


Article type: Communication
DOI: 10.1039/C8CC04079F
Citation: Chem. Commun., 2018, Accepted Manuscript
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    3D Supramolecular self-assembly of [60]fullerene hexaadducts decorated with triarylamine molecules

    O. Gavat, T. M. N. Trinh, E. Moulin, T. K. Ellis, M. maaloum, E. Buhler, G. Fleith, J. F. Nierengarten and N. GIUSEPPONE, Chem. Commun., 2018, Accepted Manuscript , DOI: 10.1039/C8CC04079F

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