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Issue 53, 2018
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Anion–π interactions of highly π-acidic dipyridinium-naphthalene diimide salts

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Abstract

A highly π-acidic dipyridinium-naphthalene diimide acceptor shows anion–π interactions with halides and PF6. Lewis basicity and redox potential of the anion affect the chemistry, and photophysical and electrochemical properties, as well as both ionic and electrical conductivities. Our results provide insights into doping, degradation and ion transport mechanisms in organic n-type semiconductors.

Graphical abstract: Anion–π interactions of highly π-acidic dipyridinium-naphthalene diimide salts

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Publication details

The article was received on 17 May 2018, accepted on 11 Jun 2018 and first published on 11 Jun 2018


Article type: Communication
DOI: 10.1039/C8CC03941K
Citation: Chem. Commun., 2018,54, 7374-7377
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    Anion–π interactions of highly π-acidic dipyridinium-naphthalene diimide salts

    T. L. D. Tam, C. K. Ng, X. Lu, Z. L. Lim and J. Wu, Chem. Commun., 2018, 54, 7374
    DOI: 10.1039/C8CC03941K

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