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Chirality sensing of choline derivatives by a triple anion helicate cage through induced circular dichroism

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Abstract

Chirality sensing of choline derivatives is achieved by a self-assembled, racemic triple anion helicate cage which exhibits induced circular dichroism (ICD) upon encapsulation of a chiral guest. The host–guest interactions were illustrated by NMR, crystal structure, CD and DFT calculations. The absolute configurations and ee values were determined by ICD.

Graphical abstract: Chirality sensing of choline derivatives by a triple anion helicate cage through induced circular dichroism

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Publication details

The article was received on 15 May 2018, accepted on 11 Jun 2018 and first published on 11 Jun 2018


Article type: Communication
DOI: 10.1039/C8CC03883J
Citation: Chem. Commun., 2018, Advance Article
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    Chirality sensing of choline derivatives by a triple anion helicate cage through induced circular dichroism

    W. Zuo, Z. Huang, Y. Zhao, W. Xu, Z. Liu, X. Yang, C. Jia and B. Wu, Chem. Commun., 2018, Advance Article , DOI: 10.1039/C8CC03883J

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