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Issue 53, 2018
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Chirality sensing of choline derivatives by a triple anion helicate cage through induced circular dichroism

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Abstract

Chirality sensing of choline derivatives is achieved by a self-assembled, racemic triple anion helicate cage which exhibits induced circular dichroism (ICD) upon encapsulation of a chiral guest. The host–guest interactions were illustrated by NMR, crystal structure, CD and DFT calculations. The absolute configurations and ee values were determined by ICD.

Graphical abstract: Chirality sensing of choline derivatives by a triple anion helicate cage through induced circular dichroism

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Publication details

The article was received on 15 May 2018, accepted on 11 Jun 2018 and first published on 11 Jun 2018


Article type: Communication
DOI: 10.1039/C8CC03883J
Citation: Chem. Commun., 2018,54, 7378-7381
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    Chirality sensing of choline derivatives by a triple anion helicate cage through induced circular dichroism

    W. Zuo, Z. Huang, Y. Zhao, W. Xu, Z. Liu, X. Yang, C. Jia and B. Wu, Chem. Commun., 2018, 54, 7378
    DOI: 10.1039/C8CC03883J

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