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Issue 55, 2018
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C–H oxygenation at tertiary carbon centers using iodine oxidant

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Abstract

An oxidation system in which iodic acid (HIO3) is used as an oxidant in the presence of N-hydroxyphthalimide (NHPI) permitted the selective hydroxylation of tertiary C–H bonds and the lactonization of carboxylic acids containing a tertiary carbon center. These reactions are operationally simple and proceed under metal-free conditions using commercially available reagents, thus offering an ideal tool for the efficient oxidation of C–H bonds at tertiary carbon centers.

Graphical abstract: C–H oxygenation at tertiary carbon centers using iodine oxidant

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Publication details

The article was received on 09 May 2018, accepted on 12 Jun 2018 and first published on 13 Jun 2018


Article type: Communication
DOI: 10.1039/C8CC03735C
Citation: Chem. Commun., 2018,54, 7609-7612
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    C–H oxygenation at tertiary carbon centers using iodine oxidant

    K. Kiyokawa, R. Ito, K. Takemoto and S. Minakata, Chem. Commun., 2018, 54, 7609
    DOI: 10.1039/C8CC03735C

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