Issue 56, 2018
From the journal:

Chemical Communications

Central metal dependent modulation of induced-fit gas uptake in molecular porphyrin solids†

Hirotomo Nishihara, ORCID logo *a   Mao Ohwada,a   Takuya Kamimura,b   Masato Nishimura,b   Hideki Tanaka, ORCID logo c   Shotaro Hiraide,c   Minoru T. Miyahara,c   Katsuhiko Ariga, ORCID logo de   Qingmin Ji,df   Jun Maruyama ORCID logo g  and  Fumito Tani ORCID logo *b  

* Corresponding authors

a Institute of Multidisciplinary Research for Advanced Materials, Tohoku University, 2-1-1, Katahira, Aoba-ku, Sendai, Japan
E-mail: hirotomo.nishihara.b1@tohoku.ac.jp

b Institute for Materials Chemistry and Engineering, Kyushu University, 744 Motooka, Nishi-ku, Fukuoka 819-0395, Japan
E-mail: tanif@ms.ifoc.kyushu-u.ac.jp

c Department of Chemical Engineering, Kyoto University, Katsura, Nishikyo, Kyoto 615-8510, Japan

d World Premier International (WPI) Research Center for Materials, Nanoarchitechtonics (MANA), National Institute for Materials Science (NIMS), 1-1 Namiki, Tsukuba, Ibaraki 305-0044, Japan

e Department of Advanced Materials Science, Graduate School of Frontier Sciences, The University of Tokyo, 5-1-5 Kashiwanoha, Kashiwa, Chiba 277-8561, Japan

f Herbert Gleiter Institute of Nanoscience, Nanjing University of Science and Technology, 200 Xiaolingwei, Jiangsu, China

g Research Division of Environmental Technology, Osaka Research Institute of Industrial Science and Technology, 1-6-50, Morinomiya, Joto-ku, Osaka 536-8553, Japan

Abstract

The induced-fit accommodation of a variety of gaseous molecules including non-polar molecules has been demonstrated in porphyrin-based supramolecular architectures for the first time. Moreover, the gas uptake behaviour can be modulated by changing the central cation of porphyrin.

Graphical abstract: Central metal dependent modulation of induced-fit gas uptake in molecular porphyrin solids

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Article information

DOI
https://doi.org/10.1039/C8CC03646B
Article type
Communication
Submitted
06 May 2018
Accepted
15 Jun 2018
First published
16 Jun 2018

Chem. Commun., 2018,54, 7822-7825

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Central metal dependent modulation of induced-fit gas uptake in molecular porphyrin solids

H. Nishihara, M. Ohwada, T. Kamimura, M. Nishimura, H. Tanaka, S. Hiraide, M. T. Miyahara, K. Ariga, Q. Ji, J. Maruyama and F. Tani, Chem. Commun., 2018, 54, 7822 DOI: 10.1039/C8CC03646B

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