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Synthesis of functionalized pyrroloindolines via a visible-light-induced radical cascade reaction: rapid synthesis of (±)-flustraminol B

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Abstract

The development of visible-light-induced synthesis of functionalized pyrroloindolines via a radical cascade reaction is reported. The reaction shows a broad substrate scope and highlights the mild nature of the reaction conditions. A range of substitutions on indole aromatic rings and N-centers is well tolerated, including a free allylic alcohol. Relying on the strategy, a rapid synthesis of (±)-flustraminol B was achieved.

Graphical abstract: Synthesis of functionalized pyrroloindolines via a visible-light-induced radical cascade reaction: rapid synthesis of (±)-flustraminol B

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Publication details

The article was received on 03 May 2018, accepted on 07 Jun 2018 and first published on 07 Jun 2018


Article type: Communication
DOI: 10.1039/C8CC03575J
Citation: Chem. Commun., 2018, Advance Article
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    Synthesis of functionalized pyrroloindolines via a visible-light-induced radical cascade reaction: rapid synthesis of (±)-flustraminol B

    K. Wu, Y. Du, Z. Wei and T. Wang, Chem. Commun., 2018, Advance Article , DOI: 10.1039/C8CC03575J

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