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Catalysis of photooxidation reactions through transformation between Cu2+ and Cu+ in TiO2-Cu-MOF composites

Abstract

Novel porous TiO2@Cu3(BTC)2 composites, which were synthesized using ionic liquids (ILs) as solvent, exhibited excellent activity for photooxidation of styrene to 4-aryl tetralones and promoting Glaser coupling reaction with O2 under light irradiation. It was discovered that the transformation between Cu2+ and Cu+ was crucial for enhancing photocatalytic performance.

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Publication details

The article was received on 01 May 2018, accepted on 14 May 2018 and first published on 14 May 2018


Article type: Communication
DOI: 10.1039/C8CC03505A
Citation: Chem. Commun., 2018, Accepted Manuscript
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    Catalysis of photooxidation reactions through transformation between Cu2+ and Cu+ in TiO2-Cu-MOF composites

    C. Chen, T. Wu, D. Yang, P. Zhang, H. Liu, Y. Yang, G. Yang and B. Han, Chem. Commun., 2018, Accepted Manuscript , DOI: 10.1039/C8CC03505A

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