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Issue 53, 2018
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Rare earth arylsilazido compounds with inequivalent secondary interactions

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Abstract

A new bulky silazido ligand, –N(SiHMe2)Dipp (Dipp = C6H3-2,6-iPr2), supports planar, three-coordinate homoleptic rare earth complexes Ln{N(SiHMe2)Dipp}3 (Ln = Sc, Y, and Lu), each containing three secondary Ln↼HSi interactions and one agostic CH bond. Y{N(SiHMe2)Dipp}3 and acetophenone react via hydrosilylation, rather than by insertion into the Y–N bond or by enolate formation.

Graphical abstract: Rare earth arylsilazido compounds with inequivalent secondary interactions

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Publication details

The article was received on 19 Apr 2018, accepted on 02 Jun 2018 and first published on 05 Jun 2018


Article type: Communication
DOI: 10.1039/C8CC03186J
Citation: Chem. Commun., 2018,54, 7318-7321
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    Rare earth arylsilazido compounds with inequivalent secondary interactions

    K. C. Boteju, S. Wan, A. Venkatesh, A. Ellern, A. J. Rossini and A. D. Sadow, Chem. Commun., 2018, 54, 7318
    DOI: 10.1039/C8CC03186J

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