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Issue 45, 2018
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Photocatalytic difunctionalisations of alkenes with N-SCN sulfoximines

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Abstract

Reacting N-Br sulfoximines with ammonium thiocyanate leads to unprecedented sulfur reagents, which add to vinyl arenes under photocatalysis via N-centered sulfoximidoyl radicals. As a result, 1,2-difunctionalised products are obtained, which can subsequently be derivatised taking advantage of the unique properties of the thiocyanate group.

Graphical abstract: Photocatalytic difunctionalisations of alkenes with N-SCN sulfoximines

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Publication details

The article was received on 20 Apr 2018, accepted on 14 May 2018 and first published on 14 May 2018


Article type: Communication
DOI: 10.1039/C8CC03178A
Citation: Chem. Commun., 2018,54, 5772-5775
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    Photocatalytic difunctionalisations of alkenes with N-SCN sulfoximines

    D. Zhang, H. Wang and C. Bolm, Chem. Commun., 2018, 54, 5772
    DOI: 10.1039/C8CC03178A

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