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Photocatalytic Difunctionalisations of Alkenes with N–SCN Sulfoximines

Abstract

Reacting N–Br sulfoximines with ammonium thiocyanate leads to unprecedented sulfur reagents, which add to vinyl arenes under photocatalysis via N-centered sulfoximidoyl radicals. As a result, 1,2-difunctionalised products are obtained, which can subsequently be derivatised taking advantage of the unique properties of the thiocyanate group.

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Publication details

The article was received on 20 Apr 2018, accepted on 14 May 2018 and first published on 14 May 2018


Article type: Communication
DOI: 10.1039/C8CC03178A
Citation: Chem. Commun., 2018, Accepted Manuscript
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    Photocatalytic Difunctionalisations of Alkenes with N–SCN Sulfoximines

    D. Zhang, H. Wang and C. Bolm, Chem. Commun., 2018, Accepted Manuscript , DOI: 10.1039/C8CC03178A

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