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Issue 51, 2018
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Synthesis and structural characterization of the first neptunium based metal–organic frameworks incorporating {Np6O8} hexanuclear clusters

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Abstract

Successful synthesis of the first transuranium metal–organic frameworks (TRU-MOFs) involving tetravalent Np4+ is reported. These compounds were obtained from the controlled hydrolysis of Np4+ in the presence of dicarboxylate ligands. The final structures contain the [Np6O4(OH)4(H2O)6]12+ unit, which were never crystallized before with tetravalent neptunium, associated with ditopic ligands.

Graphical abstract: Synthesis and structural characterization of the first neptunium based metal–organic frameworks incorporating {Np6O8} hexanuclear clusters

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Publication details

The article was received on 18 Apr 2018, accepted on 16 May 2018 and first published on 16 May 2018


Article type: Communication
DOI: 10.1039/C8CC03121E
Citation: Chem. Commun., 2018,54, 6979-6982
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    Synthesis and structural characterization of the first neptunium based metal–organic frameworks incorporating {Np6O8} hexanuclear clusters

    N. P. Martin, J. März, H. Feuchter, S. Duval, P. Roussel, N. Henry, A. Ikeda-Ohno, T. Loiseau and C. Volkringer, Chem. Commun., 2018, 54, 6979
    DOI: 10.1039/C8CC03121E

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