Jump to main content
Jump to site search


Use of a benzyl ether as a traceless hydrogen donor in anti-Markovnikov hydrofunctionalization of alkenes with xanthates

Abstract

A new protocol for anti-Markovnikov hydrofunctionalization of alkenyl alcohol O-Bn ethers was developed using xanthates as functionalizing agents in the presence of lauroyl peroxide as a radical initiator and a stoichiometric oxidant. The benzyl group serves as a traceless hydrogen donor in the remote radical hydrogen atom transfer event during the process.

Back to tab navigation

Supplementary files

Publication details

The article was received on 14 Apr 2018, accepted on 13 Jun 2018 and first published on 13 Jun 2018


Article type: Communication
DOI: 10.1039/C8CC02971G
Citation: Chem. Commun., 2018, Accepted Manuscript
  •   Request permissions

    Use of a benzyl ether as a traceless hydrogen donor in anti-Markovnikov hydrofunctionalization of alkenes with xanthates

    H. Hayashi, A. Kaga, B. Wang, F. Gagosz and S. Chiba, Chem. Commun., 2018, Accepted Manuscript , DOI: 10.1039/C8CC02971G

Search articles by author

Spotlight

Advertisements