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Two dominant self-assembly pathways to a Pd3L6 double-walled triangle

Abstract

The self-assembly process of a Pd3L6 double-walled triangle (DWT) from PdPy*4(BF4)2 (Py* indicates 3-chloropyridine) and V-shaped ditopic ligands (1) was investigated by NMR-based quantitative analysis of self-assembly process (QASAP). DWT was assembled mainly through two pathways that branch off from a dinuclear single-walled chain (SWC). In both pathways, trinuclear SWCs are firstly produced and then the macrocyclization and the formation of double-walls in the SWCs take place to lead to an incomplete DWT (Pd316Py*), which is finally converted to DWT by an intramolecular ligand exchange.

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Publication details

The article was received on 31 Mar 2018, accepted on 09 May 2018 and first published on 10 May 2018


Article type: Communication
DOI: 10.1039/C8CC02608D
Citation: Chem. Commun., 2018, Accepted Manuscript
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    Two dominant self-assembly pathways to a Pd3L6 double-walled triangle

    T. Tateishi, S. Kai, Y. Sasaki, T. Kojima, S. Takahashi and S. Hiraoka, Chem. Commun., 2018, Accepted Manuscript , DOI: 10.1039/C8CC02608D

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