Issue 42, 2018
From the journal:

Chemical Communications

Stable lead(ii) boroxides†

Adrian-Alexandru Someşan,a   Erwann Le Coz,b   Thierry Roisnel,b   Cristian Silvestru ORCID logo *a  and  Yann Sarazin ORCID logo *b  

* Corresponding authors

a Supramolecular Organic and Organometallic Chemistry Centre, Chemistry Department, Faculty of Chemistry and Chemical Engineering, Babes-Bolyai University, Cluj-Napoca RO-400028, Romania
E-mail: cristian.silvestru@ubbcluj.ro
Tel: +40 264-593833

b Univ Rennes, CNRS, ISCR (Institut des Sciences Chimiques de Rennes) – UMR 6226, Rennes F-35000, France
E-mail: yann.sarazin@univ-rennes1.fr
Tel: +33 223-233019

Abstract

The first examples of lead(II) boroxides, [Pb(OB{CH(SiMe3)2}2)2] (1) and [{N^C}PbOB{CH(SiMe3)2}2] (5; N^C = 2-Me2NCH2C6H4), were prepared via simple protocols. These structurally characterised compounds are stable and, unlike lead(II) alkoxides and siloxides, do not trigger uncontrolled formation of lead(II) oxoclusters.

Graphical abstract: Stable lead(ii) boroxides

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Article information

DOI
https://doi.org/10.1039/C8CC02459F
Article type
Communication
Submitted
27 Mar 2018
Accepted
18 Apr 2018
First published
19 Apr 2018

Chem. Commun., 2018,54, 5299-5302

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Stable lead(II) boroxides

A. Someşan, E. Le Coz, T. Roisnel, C. Silvestru and Y. Sarazin, Chem. Commun., 2018, 54, 5299 DOI: 10.1039/C8CC02459F

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