Issue 44, 2018
From the journal:

Chemical Communications

Electron transfer-induced reduction of organic halides with amines†

Takahide Fukuyama, ORCID logo a   Yuki Fujita,a   Hayato Miyoshi,a   Ilhyong Ryu, ORCID logo *ab   Shih-Chieh Kaob  and  Yen-Ku Wu ORCID logo *b  

* Corresponding authors

a Department of Chemistry, Graduate School of Science, Osaka Prefecture University, Sakai, Osaka 599-8531, Japan
E-mail: ryu@c.s.osakafu-u.ac.jp

b Department of Applied Chemistry, National Chiao Tung University, Hsinchu, Taiwan

Abstract

Reduction of a variety of organo halides was examined by using amines as a sacrificial hydrogen source. UV light-induced reduction of vinyl and aryl halides with triethylamine proceeded smoothly to give the corresponding reduced products. High temperature heating also caused the reduction and DABCO (1,4-diazabicyclo[2.2.2]octane) also served as a good reducing reagent.

Graphical abstract: Electron transfer-induced reduction of organic halides with amines

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Article information

DOI
https://doi.org/10.1039/C8CC02445F
Article type
Communication
Submitted
27 Mar 2018
Accepted
03 May 2018
First published
03 May 2018

Chem. Commun., 2018,54, 5582-5585

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Electron transfer-induced reduction of organic halides with amines

T. Fukuyama, Y. Fujita, H. Miyoshi, I. Ryu, S. Kao and Y. Wu, Chem. Commun., 2018, 54, 5582 DOI: 10.1039/C8CC02445F

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