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Issue 50, 2018
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Ambiphilic geometrically constrained phosphenium cation

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Abstract

In this work the synthesis of a geometrically constrained phosphenium cation is shown. In contrast to previously reported phosphenium cations, the geometrical constriction of the P-center in this cation makes it ambiphilic and reactive towards small molecules such as H2O, ROH and NH3.

Graphical abstract: Ambiphilic geometrically constrained phosphenium cation

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Publication details

The article was received on 26 Mar 2018, accepted on 28 May 2018 and first published on 28 May 2018


Article type: Communication
DOI: 10.1039/C8CC02423E
Citation: Chem. Commun., 2018,54, 6931-6934
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    Ambiphilic geometrically constrained phosphenium cation

    S. Volodarsky and R. Dobrovetsky, Chem. Commun., 2018, 54, 6931
    DOI: 10.1039/C8CC02423E

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