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Heterogeneous nucleation and growth of highly crystalline imine-linked covalent organic frameworks

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Abstract

A heterogeneous nucleation and growth method is reported to synthesize imine-linked covalent organic frameworks (COFs). Excellent crystallinity and a high surface area are obtained. The introduction of heterogeneous nuclei suppresses the fast precipitation of amorphous structures at the early stage while promoting the crystallization of COFs during the growth process.

Graphical abstract: Heterogeneous nucleation and growth of highly crystalline imine-linked covalent organic frameworks

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Publication details

The article was received on 26 Mar 2018, accepted on 11 May 2018 and first published on 11 May 2018


Article type: Communication
DOI: 10.1039/C8CC02381F
Citation: Chem. Commun., 2018, Advance Article
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    Heterogeneous nucleation and growth of highly crystalline imine-linked covalent organic frameworks

    Y. Yuan, B. Sun, A. Cao, D. Wang and L. Wan, Chem. Commun., 2018, Advance Article , DOI: 10.1039/C8CC02381F

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