Issue 38, 2018

Cu(ii) coordination polymers with nitrogen catenation ligands for efficient photocatalytic water oxidation

Abstract

A Cu(II) coordination polymer, [Cu(tza)2]n (Htza, tetrazole-1-acetic acid), was investigated as an efficient water oxidation catalyst in the well-established Ru(bpy)32+/S2O82− (bpy = 2,2′-bipyridine) photocatalytic system. The turnover frequency (TOF) was measured to be 1.68 s−1, which is the highest among all reported copper-based photocatalytic water oxidation systems.

Graphical abstract: Cu(ii) coordination polymers with nitrogen catenation ligands for efficient photocatalytic water oxidation

Supplementary files

Article information

Article type
Communication
Submitted
25 Mar 2018
Accepted
12 Apr 2018
First published
24 Apr 2018

Chem. Commun., 2018,54, 4794-4797

Cu(II) coordination polymers with nitrogen catenation ligands for efficient photocatalytic water oxidation

X. Jiang, B. Yang, Q. Yang, C. Tung and L. Wu, Chem. Commun., 2018, 54, 4794 DOI: 10.1039/C8CC02359J

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