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Issue 45, 2018
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A tritopic carbanionic N-heterocyclic dicarbene and its homo- and heterometallic coinage metal complexes

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Abstract

Homo (Au3)- and heterotrinuclear coinage metal complexes (Au2Ag and Au2Cu) ligated by the first tritopic carbanionic N-heterocyclic carbene (NHC) have been prepared by deprotonation of ditopic NHC digold complexes and structurally characterized by single-crystal X-ray diffraction.

Graphical abstract: A tritopic carbanionic N-heterocyclic dicarbene and its homo- and heterometallic coinage metal complexes

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Publication details

The article was received on 19 Mar 2018, accepted on 06 May 2018 and first published on 09 May 2018


Article type: Communication
DOI: 10.1039/C8CC02192A
Citation: Chem. Commun., 2018,54, 5736-5739
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    A tritopic carbanionic N-heterocyclic dicarbene and its homo- and heterometallic coinage metal complexes

    F. Zhang, X. Cao, J. Wang, J. Jiao, Y. Huang, M. Shi, P. Braunstein and J. Zhang, Chem. Commun., 2018, 54, 5736
    DOI: 10.1039/C8CC02192A

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