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The reductive aromatization of naphthalene diimide: a versatile platform for 2,7-diazapyrenes

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Abstract

The reductive aromatization of naphthalene diimide provides tetrapivaloxy-2,7-diazapyrene, which serves as a versatile platform toward peripherally substituted 2,7-diazapyrenes. Time-resolved microwave conductivity measurements demonstrated that the intrinsic electron mobility of 2,7-diazapyrene is significantly higher than that of the corresponding pyrene.

Graphical abstract: The reductive aromatization of naphthalene diimide: a versatile platform for 2,7-diazapyrenes

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Publication details

The article was received on 10 Mar 2018, accepted on 05 Apr 2018 and first published on 06 Apr 2018


Article type: Communication
DOI: 10.1039/C8CC01937A
Citation: Chem. Commun., 2018, Advance Article
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    The reductive aromatization of naphthalene diimide: a versatile platform for 2,7-diazapyrenes

    T. Nakazato, T. Kamatsuka, J. Inoue, T. Sakurai, S. Seki, H. Shinokubo and Y. Miyake, Chem. Commun., 2018, Advance Article , DOI: 10.1039/C8CC01937A

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