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Evidence for anion-binding of all-cis hexafluorocyclohexane in solution and solid state

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Abstract

We report a solution NMR and X-ray crystallographic study on the anion affinity of all-cis 1,2,3,4,5,6-hexafluorocyclohexane, which has only recently become synthetically accessible. Our results suggest that the interaction exhibits preferential 1 : 1 stoichiometry, while its strength is only moderate (e.g. Ka = 400 M−1 in acetone for Cl) and depends mainly on the size of the anion and the dielectric constant of the solvent.

Graphical abstract: Evidence for anion-binding of all-cis hexafluorocyclohexane in solution and solid state

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Publication details

The article was received on 05 Mar 2018, accepted on 05 Apr 2018 and first published on 05 Apr 2018


Article type: Communication
DOI: 10.1039/C8CC01797B
Citation: Chem. Commun., 2018, Advance Article
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    Evidence for anion-binding of all-cis hexafluorocyclohexane in solution and solid state

    O. Shyshov, K. A. Siewerth and M. von Delius, Chem. Commun., 2018, Advance Article , DOI: 10.1039/C8CC01797B

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