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Four-Component Coupling Reaction of Carbon Dioxide, Amines, Cyclic Ethers and 3-Triflyloxybenzynes for the Synthesis of Functionalized Carbamates

Abstract

A novel four-component coupling reaction of carbon dioxide, amines, cyclic ethers and 3-triflyloxybenzynes has been developed for the first time, providing an efficient method for the synthesis of a series of functionalized carbamate derivatives in moderate to high yields. The process proceeds under mild, transition metal-free and fluoride-free conditions, leading to the formations of two new C-O bond, one new C-N bond and one C-H bond in a single step.

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Publication details

The article was received on 08 Mar 2018, accepted on 04 Apr 2018 and first published on 16 Apr 2018


Article type: Communication
DOI: 10.1039/C8CC01732H
Citation: Chem. Commun., 2018, Accepted Manuscript
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    Four-Component Coupling Reaction of Carbon Dioxide, Amines, Cyclic Ethers and 3-Triflyloxybenzynes for the Synthesis of Functionalized Carbamates

    H. Jiang, W. Xiong, C. Qi, R. Cheng, H. Zhang, L. Wang and D. Yan, Chem. Commun., 2018, Accepted Manuscript , DOI: 10.1039/C8CC01732H

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