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Issue 38, 2018
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Preparation of thermochromic selenidostannates in deep eutectic solvents

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Abstract

Deep eutectic mixtures were deployed for the preparation of porous layered [Sn3Se7]n2nāˆ’ single crystals. The perforation on the layers accentuates the negative temperature dependence of its band gap, resulting in remarkable thermochromic performance. Substitution of the hydroxo group by the methyl group provides an enhanced hydrophobicity for the organic template, leading to an anhydrous product with a remarkably improved thermal stability and thus reversible thermochromic properties.

Graphical abstract: Preparation of thermochromic selenidostannates in deep eutectic solvents

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Publication details

The article was received on 27 Feb 2018, accepted on 13 Apr 2018 and first published on 16 Apr 2018


Article type: Communication
DOI: 10.1039/C8CC01614C
Citation: Chem. Commun., 2018,54, 4806-4809
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    Preparation of thermochromic selenidostannates in deep eutectic solvents

    K. Wang, D. Ding, S. Zhang, Y. Wang, W. Liu, S. Wang, S. Wang, D. Liu and C. Wang, Chem. Commun., 2018, 54, 4806
    DOI: 10.1039/C8CC01614C

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