Jump to main content
Jump to site search

Issue 44, 2018
Previous Article Next Article

A robust and unique iron(II) mosaic-like MOF

Author affiliations

Abstract

A novel extended triazole-based ligand (PM-Tria) has been synthesized and an unprecedented MOF 3D has serendipitously been formed by assembling iron(II), PM-Tria ligand and fluoride anions. This MOF contains a perfectly linear one-dimensional {Fe(II)–F}n bridging chain that shows an antiferromagnetic behaviour. Furthermore, the structure is compared with a 14th century mosaic found in the Alhambra Palace in Granada showing a surprising symmetry resemblance.

Graphical abstract: A robust and unique iron(ii) mosaic-like MOF

Back to tab navigation

Supplementary files

Publication details

The article was received on 26 Feb 2018, accepted on 30 Apr 2018 and first published on 30 Apr 2018


Article type: Communication
DOI: 10.1039/C8CC01561A
Citation: Chem. Commun., 2018,54, 5526-5529
  •   Request permissions

    A robust and unique iron(II) mosaic-like MOF

    E. Fernandez-Bartolome, J. Santos, S. Khodabakhshi, L. J. M<small xmlns="http://www.rsc.org/schema/rscart38"> <sup>c</sup> </small>Cormick, S. J. Teat, C. S. de Pipaon, J. R. Galan-Mascarós, N. Martín and J. Sanchez Costa, Chem. Commun., 2018, 54, 5526
    DOI: 10.1039/C8CC01561A

Search articles by author

Spotlight

Advertisements