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Issue 34, 2018
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Stereodivergent trifluoromethylation of N-sulfinylimines by fluoroform with either organic-superbase or organometallic-base

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Abstract

Here we have successfully demonstrated the first stereodivergent direct nucleophilic trifluoromethylation of N-sulfinylimines using the potent greenhouse gas “HFC-23, fluoroform” with an organic-superbase or an organometallic-base in high yields and selectivity.

Graphical abstract: Stereodivergent trifluoromethylation of N-sulfinylimines by fluoroform with either organic-superbase or organometallic-base

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Publication details

The article was received on 26 Feb 2018, accepted on 23 Mar 2018 and first published on 23 Mar 2018


Article type: Communication
DOI: 10.1039/C8CC01526K
Citation: Chem. Commun., 2018,54, 4294-4297
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    Stereodivergent trifluoromethylation of N-sulfinylimines by fluoroform with either organic-superbase or organometallic-base

    N. Punna, T. Saito, M. Kosobokov, E. Tokunaga, Y. Sumii and N. Shibata, Chem. Commun., 2018, 54, 4294
    DOI: 10.1039/C8CC01526K

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