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A chiral Pt12 tetrahedral cage and its use in catalytic Michael addition reaction

Abstract

Reaction of chiral cis-[(1S, 2S)-dch]Pt(NO3)2 (M) with a hexadentate ligand (L) in 3:1 stoichiometric ratio yielded a [12+4] self-assembled chiral M12L4 molecular tetrahedron (T) [where (1S, 2S)-dch =(1S, 2S)-1,2-diaminocyclohexane]. The cage T features internal 3D nanocavity with large open windows, enables it to catalyze the Michael addition reactions of a series of water-insoluble nitrostyrene derivatives with indole in (9:1) water : methanol mixture.

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Publication details

The article was received on 22 Feb 2018, accepted on 06 Apr 2018 and first published on 09 Apr 2018


Article type: Communication
DOI: 10.1039/C8CC01487F
Citation: Chem. Commun., 2018, Accepted Manuscript
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    A chiral Pt12 tetrahedral cage and its use in catalytic Michael addition reaction

    P. S. Mukherjee, I. A. Bhat, A. Devaraj, P. Howlader and K. Chi, Chem. Commun., 2018, Accepted Manuscript , DOI: 10.1039/C8CC01487F

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