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An alkaline-resistant Ag(I)-anchored pyrazolate-based metal–organic framework for chemical fixation of CO2

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Abstract

An alkaline-resistant Ag(I)-anchored metal–organic framework has been achieved via postsynthetic modification of pyrazolate-based linkers. For the first time, the resultant MOF was completely heterogeneous and recyclable over at least ten cycles in cyclic carboxylation of propargyl amines and CO2 into oxazolidinones and tetramic acids under atmospheric pressure of CO2.

Graphical abstract: An alkaline-resistant Ag(i)-anchored pyrazolate-based metal–organic framework for chemical fixation of CO2

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Publication details

The article was received on 21 Feb 2018, accepted on 04 Apr 2018 and first published on 09 Apr 2018


Article type: Communication
DOI: 10.1039/C8CC01461B
Citation: Chem. Commun., 2018, Advance Article
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    An alkaline-resistant Ag(I)-anchored pyrazolate-based metal–organic framework for chemical fixation of CO2

    H. Yang, X. Zhang, G. Zhang and H. Fei, Chem. Commun., 2018, Advance Article , DOI: 10.1039/C8CC01461B

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