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Issue 50, 2018
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An air-stable N-heterocyclic carbene iminoxyl borate radical zwitterion

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Abstract

A remarkably stable radical zwitterion derived from N-heterocyclic carbene nitric oxide and B(C6F5)3 is reported. The presented radical was generated by steric and electronic protection of the nitric oxide moiety using B(C6F5)3, which secured its stability toward air and moisture. An analogous yet less stable radical derived from C(C6H5)3+ is also synthesized and characterized.

Graphical abstract: An air-stable N-heterocyclic carbene iminoxyl borate radical zwitterion

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Publication details

The article was received on 18 Feb 2018, accepted on 26 Mar 2018 and first published on 27 Mar 2018


Article type: Communication
DOI: 10.1039/C8CC01399C
Citation: Chem. Commun., 2018,54, 6824-6827
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    An air-stable N-heterocyclic carbene iminoxyl borate radical zwitterion

    Y. Kim and E. Lee, Chem. Commun., 2018, 54, 6824
    DOI: 10.1039/C8CC01399C

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