A [FeIII(Tp)(CN)3]− scorpionate-based complex as a building block for designing ion storage hosts (Tp: hydrotrispyrazolylborate)

Juan-Ramón Jiménez; Akira Sugahara; Masashi Okubo; Atsuo Yamada; Lise-Marie Chamoreau; Laurent Lisnard; Rodrigue Lescouëzec

doi:10.1039/C8CC01374H

You do not have JavaScript enabled. Please enable JavaScript to access the full features of the site or access our non-JavaScript page.

A [Fe^III(Tp)(CN)₃]⁻ scorpionate-based complex as a building block for designing ion storage hosts (Tp: hydrotrispyrazolylborate)†

Juan-Ramón Jiménez,^a Akira Sugahara,

^b Masashi Okubo,^b Atsuo Yamada,

^b Lise-Marie Chamoreau,^a Laurent Lisnard

^a and Rodrigue Lescouëzec

*^a

Author affiliations

* Corresponding authors

^a Sorbonne Université, CNRS, Institut Parisien de Chimie Moléculaire, IPCM, 4 place Jussieu, 75252 Paris, France
E-mail: rodrigue.lescouezec@sorbonne-universite.fr

^b Department of Chemical System Engineering, School of Engineering, The University of Tokyo, Hongo 7-3-1, Bunkyo-ku, 113-8656 Tokyo, Japan

Abstract

Using a scorpionate-based complex, [Fe^III(Tp)(CN)₃]⁻, as a building block, a new cyanide-based molecular material [{Fe^III(Tp)(CN)₃}₂Ni^II(H₂O)₂]·4H₂O (1), which can be viewed as a lower dimensional model of Prussian blue analogues, was investigated as a lithium-ion storage host.

Download options Please wait...

Supplementary files

Article information

DOI: https://doi.org/10.1039/C8CC01374H
Article type: Communication
Submitted: 16 Feb 2018
Accepted: 15 Apr 2018
First published: 17 Apr 2018

Download Citation

Chem. Commun., 2018,54, 5189-5192

Author version available

Download author version (PDF)

Permissions

Request permissions

A [Fe^III(Tp)(CN)₃]⁻ scorpionate-based complex as a building block for designing ion storage hosts (Tp: hydrotrispyrazolylborate)

J. Jiménez, A. Sugahara, M. Okubo, A. Yamada, L. Chamoreau, L. Lisnard and R. Lescouëzec, Chem. Commun., 2018, 54, 5189 DOI: 10.1039/C8CC01374H

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Social activity

Fetching data from CrossRef.
This may take some time to load.

Chemical Communications