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Issue 33, 2018
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Synthesis, characterization and properties of a glycol-coordinated ε-Keggin-type Al13 chloride

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Abstract

Herein we present the first example of a glycol-coordinated ε-Keggin Al13 chloride (gl-ε-Al13), which is the first chelated version since discovery of Al13 in 1960. The molecular structure consists of [AlO4Al12(OH)12(OC2H4OH)12]Cl7·H2O units with chelating mono-anionic ethylene glycol units replacing one bridging and one terminal oxygen site.

Graphical abstract: Synthesis, characterization and properties of a glycol-coordinated ε-Keggin-type Al13 chloride

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Publication details

The article was received on 16 Feb 2018, accepted on 28 Mar 2018 and first published on 29 Mar 2018


Article type: Communication
DOI: 10.1039/C8CC01363B
Citation: Chem. Commun., 2018,54, 4148-4151
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    Synthesis, characterization and properties of a glycol-coordinated ε-Keggin-type Al13 chloride

    B. Gu, C. Sun, J. C. Fettinger, W. H. Casey, A. Dikhtiarenko, J. Gascon, K. Koichumanova, K. Babu Sai Sankar Gupta, H. Jan Heeres and S. He, Chem. Commun., 2018, 54, 4148
    DOI: 10.1039/C8CC01363B

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