Jump to main content
Jump to site search


N-Heterocyclic carbene-based ruthenium-hydride catalysts for the synthesis of unsymmetrically functionalized double-decker silsesquioxanes

Author affiliations

Abstract

Ruthenium–N-heterocyclic carbene complexes with the generic formula [RuHCl(CO)(NHC)(PCy3)] exhibit a high catalytic activity toward the (E)-selective silylative coupling of divinyl-substituted double-decker silsesquioxanes with two distinctly substituted styrenes. This process leads to a novel class of unsymmetrically functionalized silsesquioxane derivatives.

Graphical abstract: N-Heterocyclic carbene-based ruthenium-hydride catalysts for the synthesis of unsymmetrically functionalized double-decker silsesquioxanes

Back to tab navigation

Supplementary files

Publication details

The article was received on 14 Feb 2018, accepted on 29 Mar 2018 and first published on 11 Apr 2018


Article type: Communication
DOI: 10.1039/C8CC01316K
Citation: Chem. Commun., 2018, Advance Article
  •   Request permissions

    N-Heterocyclic carbene-based ruthenium-hydride catalysts for the synthesis of unsymmetrically functionalized double-decker silsesquioxanes

    P. Żak, L. Delaude, B. Dudziec and B. Marciniec, Chem. Commun., 2018, Advance Article , DOI: 10.1039/C8CC01316K

Search articles by author

Spotlight

Advertisements