Issue 34, 2018

N-Heterocyclic carbene-based ruthenium-hydride catalysts for the synthesis of unsymmetrically functionalized double-decker silsesquioxanes

Abstract

Ruthenium–N-heterocyclic carbene complexes with the generic formula [RuHCl(CO)(NHC)(PCy3)] exhibit a high catalytic activity toward the (E)-selective silylative coupling of divinyl-substituted double-decker silsesquioxanes with two distinctly substituted styrenes. This process leads to a novel class of unsymmetrically functionalized silsesquioxane derivatives.

Graphical abstract: N-Heterocyclic carbene-based ruthenium-hydride catalysts for the synthesis of unsymmetrically functionalized double-decker silsesquioxanes

Supplementary files

Article information

Article type
Communication
Submitted
14 Feb 2018
Accepted
29 Mar 2018
First published
11 Apr 2018

Chem. Commun., 2018,54, 4306-4309

N-Heterocyclic carbene-based ruthenium-hydride catalysts for the synthesis of unsymmetrically functionalized double-decker silsesquioxanes

P. Żak, L. Delaude, B. Dudziec and B. Marciniec, Chem. Commun., 2018, 54, 4306 DOI: 10.1039/C8CC01316K

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