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Metallophthalocyanine-based redox active metal–organic conjugated microporous polymers for OER catalysis

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Abstract

We report the design and synthesis of two Co2+ and Zn2+ phthalocyanine (PC)-based redox active metal–organic conjugated microporous polymers (MO-CMP), CoCMP and ZnCMP, respectively, obtained by a Schiff base condensation reaction. CoCMP, where Co2+ is stabilized by N4-coordination of PC, has shown stable and efficient electrocatalytic activity towards the OER with a low overpotential of 340 mV.

Graphical abstract: Metallophthalocyanine-based redox active metal–organic conjugated microporous polymers for OER catalysis

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Publication details

The article was received on 13 Feb 2018, accepted on 27 Mar 2018 and first published on 29 Mar 2018


Article type: Communication
DOI: 10.1039/C8CC01291A
Citation: Chem. Commun., 2018, Advance Article
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    Metallophthalocyanine-based redox active metal–organic conjugated microporous polymers for OER catalysis

    A. Singh, S. Roy, C. Das, D. Samanta and T. K. Maji, Chem. Commun., 2018, Advance Article , DOI: 10.1039/C8CC01291A

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