Jump to main content
Jump to site search

Issue 35, 2018
Previous Article Next Article

Palladium-catalyzed aerobic regio- and stereo-selective olefination reactions of phenols and acrylates via direct dehydrogenative C(sp2)–O cross-coupling

Author affiliations

Abstract

An efficient olefination protocol for the oxidative dehydrogenation of phenols and acrylates has been achieved using a palladium catalyst and O2 as the sole oxidant. This reaction exhibits high regio- and stereo-selectivity (E-isomers) with moderate to excellent isolated yields and a wide substrate scope (32 examples) including ethyl vinyl ketone and endofolliculina.

Graphical abstract: Palladium-catalyzed aerobic regio- and stereo-selective olefination reactions of phenols and acrylates via direct dehydrogenative C(sp2)–O cross-coupling

Back to tab navigation

Supplementary files

Publication details

The article was received on 11 Feb 2018, accepted on 04 Apr 2018 and first published on 05 Apr 2018


Article type: Communication
DOI: 10.1039/C8CC01226A
Citation: Chem. Commun., 2018,54, 4437-4440
  •   Request permissions

    Palladium-catalyzed aerobic regio- and stereo-selective olefination reactions of phenols and acrylates via direct dehydrogenative C(sp2)–O cross-coupling

    Y. Wu, D. Xie, Z. Zang, C. Zhou and G. Cai, Chem. Commun., 2018, 54, 4437
    DOI: 10.1039/C8CC01226A

Search articles by author

Spotlight

Advertisements