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Issue 34, 2018
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Sulfonate, sulfide and thiolate ligands into an ultrasmall nanocluster: [Ag40.13Cu13.87S19(tBuS)20(tBuSO3)12]

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Abstract

A novel Ag–Cu bimetallic nanocluster, Ag40.13Cu13.87S19(tBuS)20(tBuSO3)12, has been synthesized by precise control. The crystal structure reveals that the alloy cluster consists of a Cu10Ag2S7 core, a M42(tBuS)20(tBuSO3)12 shell and another 12 bare S atoms. The sulfonate ligand is observed in NCs for the first time via in situ oxidation of thiolate.

Graphical abstract: Sulfonate, sulfide and thiolate ligands into an ultrasmall nanocluster: [Ag40.13Cu13.87S19(tBuS)20(tBuSO3)12]

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Publication details

The article was received on 05 Feb 2018, accepted on 30 Mar 2018 and first published on 03 Apr 2018


Article type: Communication
DOI: 10.1039/C8CC00985F
Citation: Chem. Commun., 2018,54, 4314-4316
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    Sulfonate, sulfide and thiolate ligands into an ultrasmall nanocluster: [Ag40.13Cu13.87S19(tBuS)20(tBuSO3)12]

    S. Yang, J. Chai, H. Chong, Y. Song, H. Yu and M. Zhu, Chem. Commun., 2018, 54, 4314
    DOI: 10.1039/C8CC00985F

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