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Issue 20, 2018
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An electrophilic reagent for the synthesis of OCHFMe-containing molecules

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Abstract

Herein the synthesis of a novel and bench stable electrophilic reagent to construct the OCFHMe motif from O-nucleophiles has been described. This sulfonium salt, readily obtained in 5 steps, reacted with various phenols and alcohols. The resulting products, including complex molecules, were obtained in good yields. This reagent was also used for the functionalization of thiol derivatives.

Graphical abstract: An electrophilic reagent for the synthesis of OCHFMe-containing molecules

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Publication details

The article was received on 02 Feb 2018, accepted on 07 Feb 2018 and first published on 07 Feb 2018


Article type: Communication
DOI: 10.1039/C8CC00921J
Citation: Chem. Commun., 2018,54, 2491-2493
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    An electrophilic reagent for the synthesis of OCHFMe-containing molecules

    E. Carbonnel, X. Pannecoucke, T. Besset, P. Jubault and T. Poisson, Chem. Commun., 2018, 54, 2491
    DOI: 10.1039/C8CC00921J

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