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Issue 24, 2018
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Multifunctional monomers based on vinyl sulfonates and vinyl sulfonamides for crosslinking thiol-Michael polymerizations: monomer reactivity and mechanical behavior

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Abstract

Multifunctional vinyl sulfonates and vinyl sulfonamides were conveniently synthesized and assessed in thiol-Michael crosslinking polymerizations. The monomer reactivities, mechanical behavior and hydrolytic properties were analyzed and compared with those of analogous thiol–acrylate polymerizations. Materials with a broad range of mechanical properties and diverse hydrolytic stabilities were obtained.

Graphical abstract: Multifunctional monomers based on vinyl sulfonates and vinyl sulfonamides for crosslinking thiol-Michael polymerizations: monomer reactivity and mechanical behavior

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Publication details

The article was received on 30 Jan 2018, accepted on 28 Feb 2018 and first published on 07 Mar 2018


Article type: Communication
DOI: 10.1039/C8CC00782A
Citation: Chem. Commun., 2018,54, 3034-3037
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    Multifunctional monomers based on vinyl sulfonates and vinyl sulfonamides for crosslinking thiol-Michael polymerizations: monomer reactivity and mechanical behavior

    J. Sinha, M. Podgórski, S. Huang and C. N. Bowman, Chem. Commun., 2018, 54, 3034
    DOI: 10.1039/C8CC00782A

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