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Issue 23, 2018
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Synthesis, crystal structure and reactivity of η2-thiophyne Ni complexes

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Abstract

The first synthesis and crystal structures of five-membered ring aryne complexes, Ni(dcpe)(η2-thiophyne) and Ni(dcpe)(η2-benzo[b]thiophyne), are described. The aryne fragments retain considerable aromatic character and the two coordinated carbon atoms exhibit distinct reactivity due to their asymmetric nature.

Graphical abstract: Synthesis, crystal structure and reactivity of η2-thiophyne Ni complexes

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Publication details

The article was received on 27 Jan 2018, accepted on 20 Feb 2018 and first published on 23 Feb 2018


Article type: Communication
DOI: 10.1039/C8CC00705E
Citation: Chem. Commun., 2018,54, 2918-2921
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    Synthesis, crystal structure and reactivity of η2-thiophyne Ni complexes

    M. Terada, Y. Nishii and M. Miura, Chem. Commun., 2018, 54, 2918
    DOI: 10.1039/C8CC00705E

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