Issue 23, 2018
From the journal:

Chemical Communications

Synthesis, crystal structure and reactivity of η2-thiophyne Ni complexes†

Misaki Terada,a   Yuji Nishii*b  and  Masahiro Miura ORCID logo *a  

* Corresponding authors

a Department of Applied Chemistry, Graduate School of Engineering, Osaka University Suita, Osaka 565-0871, Japan
E-mail: miura@chem.eng.osaka-u.ac.jp

b Frontier Research Base for Global Young Researchers, Graduate School of Engineering, Osaka University, Suita, Osaka 565-0871, Japan
E-mail: y_nishii@chem.eng.osaka-u.ac.jp

Abstract

The first synthesis and crystal structures of five-membered ring aryne complexes, Ni(dcpe)(η2-thiophyne) and Ni(dcpe)(η2-benzo[b]thiophyne), are described. The aryne fragments retain considerable aromatic character and the two coordinated carbon atoms exhibit distinct reactivity due to their asymmetric nature.

Graphical abstract: Synthesis, crystal structure and reactivity of η2-thiophyne Ni complexes

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Article information

DOI
https://doi.org/10.1039/C8CC00705E
Article type
Communication
Submitted
27 Jan 2018
Accepted
20 Feb 2018
First published
23 Feb 2018

Chem. Commun., 2018,54, 2918-2921

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Synthesis, crystal structure and reactivity of η2-thiophyne Ni complexes

M. Terada, Y. Nishii and M. Miura, Chem. Commun., 2018, 54, 2918 DOI: 10.1039/C8CC00705E

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