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Issue 18, 2018
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Synthesis of polyfluoroarene-substituted benzofuran derivatives via cooperative Pd/Cu catalysis

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Abstract

A cooperative Pd/Cu-catalyzed dual C–H bond activation of electron-deficient polyfluoroarenes with aryl halides is developed. This protocol provides a unique and strategically distinct access to a variety of polyfluoroarene-substituted benzofuran derivatives. This is the first example of the introduction of electron-deficient arenes to a Catellani-type reaction.

Graphical abstract: Synthesis of polyfluoroarene-substituted benzofuran derivatives via cooperative Pd/Cu catalysis

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Publication details

The article was received on 20 Jan 2018, accepted on 06 Feb 2018 and first published on 06 Feb 2018


Article type: Communication
DOI: 10.1039/C8CC00489G
Citation: Chem. Commun., 2018,54, 2256-2259
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    Synthesis of polyfluoroarene-substituted benzofuran derivatives via cooperative Pd/Cu catalysis

    Y. Shen, X. Wu, S. Chen, Y. Xia and Y. Liang, Chem. Commun., 2018, 54, 2256
    DOI: 10.1039/C8CC00489G

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