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Issue 26, 2018
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Iron polypyridyl catalysts assembled on metal oxide semiconductors for photocatalytic hydrogen generation

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Abstract

A series of Fe(III) complexes was recently reported that are active for photocatalytic hydrogen generation when paired with fluorescein and triethylamine. Herein we report an Fe(III) complex immobilized on TiO2 and SrTiO3 that is significantly more active than the homogeneous system, achieving up to 7800 turnovers in 31 hours.

Graphical abstract: Iron polypyridyl catalysts assembled on metal oxide semiconductors for photocatalytic hydrogen generation

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Publication details

The article was received on 18 Jan 2018, accepted on 07 Mar 2018 and first published on 07 Mar 2018


Article type: Communication
DOI: 10.1039/C8CC00453F
Citation: Chem. Commun., 2018,54, 3290-3293
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    Iron polypyridyl catalysts assembled on metal oxide semiconductors for photocatalytic hydrogen generation

    N. A. Race, W. Zhang, M. E. Screen, B. A. Barden and W. R. McNamara, Chem. Commun., 2018, 54, 3290
    DOI: 10.1039/C8CC00453F

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