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Issue 27, 2018
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Aggregation-induced emission of [3]cumulenes functionalized with heptagon-containing polyphenylenes

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Abstract

Turning on the fluorescence of [3]cumulenes: we report the luminescence at room temperature upon aggregation of [3]cumulenes functionalized with propeller-like heptagon-containing polyphenylenes. These endgroups turn on the emission of a [3]cumulene by steric protection and restriction of their intramolecular rotations in the aggregates.

Graphical abstract: Aggregation-induced emission of [3]cumulenes functionalized with heptagon-containing polyphenylenes

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Publication details

The article was received on 16 Jan 2018, accepted on 05 Mar 2018 and first published on 06 Mar 2018


Article type: Communication
DOI: 10.1039/C8CC00386F
Citation: Chem. Commun., 2018,54, 3359-3362
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    Aggregation-induced emission of [3]cumulenes functionalized with heptagon-containing polyphenylenes

    V. G. Jiménez, R. Tapia, M. A. Medel, I. F. A. Mariz, T. Ribeiro, V. Blanco, J. M. Cuerva, E. Maçôas and A. G. Campaña, Chem. Commun., 2018, 54, 3359
    DOI: 10.1039/C8CC00386F

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