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Issue 20, 2018
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Kinetic stabilization of a Ni(II) bis(dithiobenzoate)-type complex achieved using three-dimensional insulation by a [1]rotaxane structure

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Abstract

We describe herein the synthesis of a Ni(II) bis(dithiobenzoate)-type complex three-dimensionally insulated by a [1]rotaxane structure to reveal the importance of the insulation. Under cyclic voltammetry conditions, the complex showed a stable and reversible redox behavior in contrast to a non-insulated reference complex, clearly demonstrating the effectiveness of the rotaxane-type insulation as a new method of kinetic metal complex stabilization.

Graphical abstract: Kinetic stabilization of a Ni(ii) bis(dithiobenzoate)-type complex achieved using three-dimensional insulation by a [1]rotaxane structure

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Publication details

The article was received on 15 Jan 2018, accepted on 05 Feb 2018 and first published on 05 Feb 2018


Article type: Communication
DOI: 10.1039/C8CC00351C
Citation: Chem. Commun., 2018,54, 2487-2490
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    Kinetic stabilization of a Ni(II) bis(dithiobenzoate)-type complex achieved using three-dimensional insulation by a [1]rotaxane structure

    T. Hosomi, R. Harada, H. Masai, T. Fujihara, Y. Tsuji and J. Terao, Chem. Commun., 2018, 54, 2487
    DOI: 10.1039/C8CC00351C

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