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Issue 16, 2018
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Visible-light-induced oxidative difunctionalization of styrenes: synthesis of α-trifluoromethylthio-substituted ketones

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Abstract

A novel and practical synthesis of α-trifluoromethylthio-substituted ketones has been accomplished through the visible-light-induced aerobic oxidation of styrenes. The protocol employs the combination of CF3SO2Na and CS2 as a new source of SCF3 radicals in the presence of eosin Y as a photoredox catalyst.

Graphical abstract: Visible-light-induced oxidative difunctionalization of styrenes: synthesis of α-trifluoromethylthio-substituted ketones

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Publication details

The article was received on 30 Dec 2017, accepted on 29 Jan 2018 and first published on 29 Jan 2018


Article type: Communication
DOI: 10.1039/C7CC09953C
Citation: Chem. Commun., 2018,54, 1976-1979
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    Visible-light-induced oxidative difunctionalization of styrenes: synthesis of α-trifluoromethylthio-substituted ketones

    A. K. Yadav and K. N. Singh, Chem. Commun., 2018, 54, 1976
    DOI: 10.1039/C7CC09953C

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