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Issue 18, 2018
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Intermolecular chemo- and regioselective aromatic C–H amination of alkoxyarenes promoted by rhodium nitrenoids

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Abstract

Intermolecular aromatic C(sp2)–H amination promoted by neutral rhodium nitrenoids has been developed. The reactions proceeded with various oxygen-substituted arenes (1.5 equiv.) in a chemo- and regioselective manner. The aromatic C(sp2)–H amination took place at the para position of the oxygen substituent in the presence of benzylic C(sp3)–H bonds and/or C(sp3)–H bonds α to ethereal oxygen.

Graphical abstract: Intermolecular chemo- and regioselective aromatic C–H amination of alkoxyarenes promoted by rhodium nitrenoids

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Publication details

The article was received on 30 Dec 2017, accepted on 31 Jan 2018 and first published on 31 Jan 2018


Article type: Communication
DOI: 10.1039/C7CC09952E
Citation: Chem. Commun., 2018,54, 2264-2267
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    Intermolecular chemo- and regioselective aromatic C–H amination of alkoxyarenes promoted by rhodium nitrenoids

    K. Arai, Y. Ueda, K. Morisaki, T. Furuta, T. Sasamori, N. Tokitoh and T. Kawabata, Chem. Commun., 2018, 54, 2264
    DOI: 10.1039/C7CC09952E

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