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Issue 54, 2018
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Ni2[LnCl6] (Ln = EuII, CeII, GdII): the first LnII compounds stabilized in a pure inorganic lattice

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Abstract

Here we report the first examples of 3d–4f compounds based on LnII cations. We have obtained a series of Ni2[LnCl6] isostructural compounds where LnII = Ce 1, Eu 2 and Gd 3 which were characterized in a cubic crystalline system with a Fm[3 with combining macron]m space group. Magnetic and optical characterization was also performed on this new class of compounds.

Graphical abstract: Ni2[LnCl6] (Ln = EuII, CeII, GdII): the first LnII compounds stabilized in a pure inorganic lattice

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Publication details

The article was received on 29 Dec 2017, accepted on 11 Jun 2018 and first published on 11 Jun 2018


Article type: Communication
DOI: 10.1039/C7CC09921E
Citation: Chem. Commun., 2018,54, 7531-7534
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    Ni2[LnCl6] (Ln = EuII, CeII, GdII): the first LnII compounds stabilized in a pure inorganic lattice

    B. Baldo, F. Rubio, E. Flores, A. Vega, N. Audebrand, D. Venegas-Yazigi and V. Paredes-García, Chem. Commun., 2018, 54, 7531
    DOI: 10.1039/C7CC09921E

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