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Ni2[LnCl6] (Ln= EuII, CeII, GdII). The first LnII compounds stabilized in a pure inorganic lattice

Abstract

Here we report the first examples of 3d-4f compounds based on LnII cations. We have obtained a series of Ni2[LnCl6] isostructural compounds where LnII=Ce 1, Eu 2 and Gd 3 which were characterized in the cubic crystalline system with a Fm3 @#x0305;m space group. Magnetic and optical characterization were also performed on this new class of compounds.

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Publication details

The article was received on 29 Dec 2017, accepted on 11 Jun 2018 and first published on 11 Jun 2018


Article type: Communication
DOI: 10.1039/C7CC09921E
Citation: Chem. Commun., 2018, Accepted Manuscript
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    Ni2[LnCl6] (Ln= EuII, CeII, GdII). The first LnII compounds stabilized in a pure inorganic lattice

    B. Baldo, F. Rubio, E. Flores, A. Vega, N. Audebrand, D. Venegas-Yazigi and V. Paredes-Garcia, Chem. Commun., 2018, Accepted Manuscript , DOI: 10.1039/C7CC09921E

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