A highly stable MnII phosphonate as a highly efficient catalyst for CO2 fixation under ambient conditions

Yang Yang; Chao-Ying Gao; Hong-Rui Tian; Jing Ai; Xue Min; Zhong-Ming Sun

doi:10.1039/C7CC09867G

You do not have JavaScript enabled. Please enable JavaScript to access the full features of the site or access our non-JavaScript page.

A highly stable Mn^II phosphonate as a highly efficient catalyst for CO₂ fixation under ambient conditions†

Yang Yang,

‡^a Chao-Ying Gao,‡^ab Hong-Rui Tian,

^b Jing Ai,^b Xue Min^b and Zhong-Ming Sun

*^b

Author affiliations

* Corresponding authors

^a Inner Mongolia Key Lab of Chemistry of Natural Products and Synthesis of Functional Molecules, College of Chemistry and Chemical Engineering, Inner Mongolia University for the Nationalities (IMUN), Tongliao 028000, People's Republic of China

^b State Key Laboratory of Rare Earth Resource Utilization, Changchun Institute of Applied Chemistry, Chinese Academy of Sciences, 5625 Renmin Street, Changchun, Jilin 130022, China
E-mail: szm@ciac.ac.cn
Web: http://zhongmingsun.weebly.com

Abstract

With coordinatively unsaturated metal centers decorating the channel walls, a Mn^II phosphonate exhibits highly efficient and substrate size-selective catalysis in the context of CO₂ chemical conversion into cyclic carbonates under 1 atm pressure and at room temperature, proving to be a promising heterogeneous catalyst in an eco-friendly and energy efficient way.

Download options Please wait...

Supplementary files

Article information

DOI: https://doi.org/10.1039/C7CC09867G
Article type: Communication
Submitted: 26 Dec 2017
Accepted: 15 Jan 2018
First published: 15 Jan 2018

Download Citation

Chem. Commun., 2018,54, 1758-1761

Permissions

Request permissions

A highly stable Mn^II phosphonate as a highly efficient catalyst for CO₂ fixation under ambient conditions

Y. Yang, C. Gao, H. Tian, J. Ai, X. Min and Z. Sun, Chem. Commun., 2018, 54, 1758 DOI: 10.1039/C7CC09867G

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Social activity

Fetching data from CrossRef.
This may take some time to load.

Chemical Communications