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Issue 20, 2018
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PBP bridged [3]ferrocenophane: a bisphosphanylborane with a redox trigger

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Abstract

Stereospecific access to the unprecedented P–B–P bridged [3]ferrocenophane Fe(C5H4PtBu)2BMes is presented. In contrast to acyclic ferrocenylphosphanes, we find evidence for a shift of spin-density from Fe to P upon pyramidal inversion of the P centers in the mono-cation; the latter has a lifetime of τ = 0.31(4) s.

Graphical abstract: PBP bridged [3]ferrocenophane: a bisphosphanylborane with a redox trigger

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Publication details

The article was received on 21 Dec 2017, accepted on 17 Jan 2018 and first published on 18 Jan 2018


Article type: Communication
DOI: 10.1039/C7CC09759J
Citation: Chem. Commun., 2018,54, 2471-2474
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    PBP bridged [3]ferrocenophane: a bisphosphanylborane with a redox trigger

    A. Lik, D. Kargin, S. Isenberg, Z. Kelemen, R. Pietschnig and H. Helten, Chem. Commun., 2018, 54, 2471
    DOI: 10.1039/C7CC09759J

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